Is there a way I can identify that two officials can't be assigned to work on the same game together?

Yes, that can be done using the Partner Block Systems. The Partner Block System would need to be turn on in your System Settings (they are ON by default). After they are turned on, you can edit the blocks under Administrative Forms where you can block officials from working together. Additionally, you can use the other block systems to also block officials from working certain teams, leagues, game codes/levels, positions, venues, etc.

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